I prefer so called "Hard SciFi" which tries to pay attention to the known laws of physics when possible, so my favorite books usually have this in common.
Good Books:
Metro 2033 - So descriptive, such a great world. It's a slow burn ghost story in a rich clostrophobic world.
The Takeshi Kovacs Trilogy
Altered Carbon - The first and best book in the series, it's a masterpeice
Broken Angels - The second book, not as good as the first, but still some cool ideas
Rendezvous with Rama - One of my favorites, great feeling of exploration and some really solid ideas in it
The Three Body Problem Trilogy - This series, especailly book 2 and 3, are jam packed with some of the wildest, most well thought out SciFi ideas I've ever come across. It's just mind blowing.
Neuromancer - Known as the grand daddy of Cyberpunk, and deservidly so. I don't know how it took me so long to get to this one.
The Long Way to a Small, Angry Planet - This book was a wounderful suprise. The author is the rare bread that can write well thought out SciFi, AND good characters. It felt like reading a FireFly book.
The Lost Fleet - This series is 11 books long. And the writing is not, how you say... good. But if you're really hard up for military SciFi, it's quite a good depiction of hard-scifi space battles.